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Continue Mcqs on chemical kinetics with answers Resources for students Multiple Choice Questions Teacher Resources Browse Figures: All subjects Pharmacy Learn more: Online Resource Centres VLE/CMS Content Test Banks From our catalog pages: Find a textbook Find your local representative Reply to the following questions and then press 'Submit' to get your score. Congratulations - you have completed Topic: Chemistry Kinetics, Test No.: 03, Total MCQs: 15.You have scored %%%%%%%%%TOTAL%. Your performance has been evaluated in %%RATING% Your answers are highlighted below. There are 15 questions to complete. Description This Kinetics Chemistry Mock Test for Chemistry helps you for every Chemistry Input Exam. This contains 20 multiple-choice questions for Chemistry Chemistry Kinetics (mcq) to study with solutions a complete bank question. Fixed questions answer in this Chemical Kinetics quiz give you a good mix of easy questions and difficult questions. Chemistry students will definitely take this exercise of kinetic chemistry for a better result in the examination. You can find additional questions about Chemistry Kinetics, long and short questions for Chemistry on EduRev and also looking over. If A reacts to form B or C based on reactions, if E1 is the activation energy for the first reaction and E2 is the activation energy for the second reaction then Ea, the activation energy observed for the disappearance of A is Solution: The following reaction was carried out in water the initial concentration of was 0.25 molL-1 and the concentration after 10 min was 0.23 molL-1. The disappearance rate of I- (in untis of M min-1) and the emergence rate of I2 . For reaction, A + B → C +D, Δh = 20 kJ/mole. The reaction activation energy forward is 85 kJ/mole. Reverse Reaction Solution Activation Energy: *Answer can contain only numerical values The reaction order is ___________________ Solution: For theorder when concentration is interrupted interrupteddouble. *Answer can contain only numerical values For the following sequential reaction, the time when [B] maximum is ______(in sec). Solution: *Answer can contain only numerical values The percentage transmittance of a solution with absorption (optic density) 1.0 is __________ Solution: Which of the following curves represent a zero order reaction Solution: A catalyst increases the chemical reaction rate of (1) by increasing the activation energy (2) by decreasing the activation energy (3) by increasing the K.E. average of the molecule (4) by increasing the number of active molecules. Solution: The elementary reaction rate at 25oC It is given by rate = 1.7 x 10-18[H2][I2] - 2.4 x 10-21 [HI] The decomposition rate of HI gaeseous at H2 and I2 at 25o C is given by the constant balance for the formation of HI from H2 and I2 to 25o C is Solution: Is the constant time τ necessary for a reactor to fall to 1/e of its initial value then? Solution: For the first order reaction, A is 4.3 x 1013 s-1 and Ea is 103.35 KJ/mole. The value of k to 300K is Solution: Frequency factors for a non-molecular gas reaction that occurs at 473K is 2.5×1013 s–1 . The activation entropy value is Solution: Cyclohexane inter converts between a chair and a boat structure. The activation parameters for reaction from chair to the shape of the molecule boat are Gibbs' standard energy value and rate constant and rate constant for this reaction to 325K Solution: The Co(g) reaction rate law to form phosgen (Cl2CO) shows that the following mechanism is consistent with this rate law (Fast Balance) (Slow) where M is any gas molecule present in the reaction container. The value of kobs in terms of rate constants for the individual. Phases of the reaction mechanism Solution: Using the third step of the reaction mechanism to write d[CL2CO] / dt andcan contain only numerical values A substance, when dissolved in water at 10-3 M, absorbs 10% of radiation incident in a path of 1 cm long. What should be the concentration of the solution if it were to absorb 90% of the same radiation? Solution: *Answer can contain only numerical values For a reaction with the equation of the rate - dc/dt = kc2, Co and C are the concentration of the reactor at zero time and t respectively. If 10 minutes were needed to C0 to become C0/2 the time needed for Co to become C0/4 is ______min. (The answer should be a whole one). Solution: For integration taking time 0 to t, we get ...(s) *Answer can contain only numerical values The concentration of the non-competitive inhibitor (k1 = 2.9 x 10-4 Moldovam-3) required to produce 90% inhibiting a catalyst reaction of the enzyme is ________mol dm-3. (Get out two decimal points). Solution: ...(i) ...(ii)(i)(i)/(iii), we get *The answer may contain only numerical values During the nuclear explosion, one of the products is 90Sr with half-life is 28.1 year. If 1μg or 90Sr has been absorbed into the bones of a newborn instead of calcium. How much of it will remain after 10 year if it is not metabolically lost? (in units of μg) (Sent two decimal points). Solution: *Answer can contain only numerical values In a homogeneous catalytic reaction, 1.0 M of a substrate band, 1.0 μM of a 1.0 mM catalyst yield of a product in 10S. The frequency of turnover (TOF) of the reaction (s-1) is __________(response should be an entire) Solution: In the Linewear Burk plot of (initial cut)–1 vs (initial substrate concentration)–1. For a catalyzed enzyme reacts by following Michael Menten's mechanism. The interception is 6000 M–1. If the initial concentration of the enzyme is 1×10–5 M. The number of laps is Solution: We compiled NCERT MCQ questions for Class Chemistry 12 Chapter 4 Chemistry Kinetics withPdf free download covering the entire program. Practice MCQ questions for class chemistry 12 with answers on a onebase and score well in exams. refer to questions of answers of the class 12 mcq of chemical kinetics with a detailed explanation. chemical kinetics class 12 mcq questions with answers question 1. for a chemical reaction, x + 2y → z, if the z emergence rate is 0.50 molecules per liter per hour, then the y disappearance rate is (a) 0.5 mol L-1 hr-1 (b) 1.0 mol L-1 hr-1 (c) 0.25 mol L-1 hr-1 (d) cannot be expected answer: (b) 1.0 mol L-1 hr-1 question 2. for the reaction, no2 (g) + co (g) → no (g), the correct expression for the reaction rate is (a) rate = (\frac {-d[NO_2]}{dt}\) (b) rate = (\frac {-d[CO_2]}{dt}\) (c) rate = (\frac {d[NO_2]-d[CO]}{\ (a) rate = (\frac {-d[NO_2]}{dt}\) question 3. the rate of a reaction is determined mainly by the slower step. this step is called (a) step determination rate (b) activation step (c) reaction step (d) none of these. reply: (a) rate which determines the question step 4. high molecular reaction is rare because (a) many body collisions have a low probability. (b) many bodily collisions are not energetically favored. (c) the activation energy of many body collisions is very large (d) the very high concentration is necessary for such reactions. reply: (a) many bodily collisions have a low probability. Question 5. for a chemical reaction to → b, it turns out that the rate of reaction is quardruples when the concentration of a is doubled. the rate expression for the reaction is, rate = k [A]n where the value of n is (a) 1 (b) 2 (c) 0 (d) 3 answer: Question 6. on increase of the temperature of the reaction system of 10° the reaction rate becomes almost double. the most appropriate reason for this is that (a) activation energy decreases by temperature increases (b) the fraction of molecules having threshold energy increases (c) increases the frequencyCollision (d) The threshold energy value decreases. decreases.Answer: (b) The fraction of molecules with threshold energy increases demand 7. The half-life period of any first-order reaction (a) is half of the specific rate constant (b) is always the same regardless of reaction (c) is independent of the initial concentration (d) directly proportional to the initial concentration of reactive. Answer: (c) is independent of the initial concentration Question 8. The constant rate of reaction of 2nd order involves (a) concentration (b) concentration and time (c) time only (d) neither time nor concentration. Answer: (b) concentration and time Question 9. A zero order reaction A → Products, has constant rate 10-2 harassment L-1 s-1. If a process has started with 10 A-half in a one-liter container, the number of reagent molecules after 10 minutes will be (a) 10 (b) 5 (c) 6 (d) 4. Answer: (d) 4. Question 10. For which of the following reactions, is the temperature coefficient maximum? (a) A → B : Ea = 50 kJ (b) P → Q : Ea = 40 kj (c) X → Y : Ea = 60kJ (d) W → Z : Ea = 80kJ Answer: (d) W → Z: Ea = 80kJ Question 11. A hypothetical reaction 2p + q → s + r has constant rate as 2.0 × 10-3 mol L-1 s-1. The order of reaction is (a) unpredictable (b) zero (c) one (d) two Answer: Question 12. The ratio t7/8 : t1/2 for the first order is (a) 3 (b) 5 (c) 2 (d) 7 Response: (a) 3 Question 13. The molecularity of the reaction cannot be (a) 1 (b) 2 (c) 1.5 (d) 3. Answer: (c) 1.5 Question 14. For the first order reaction, the half-life is independent of (a) catalyst (b) temperature (c) both catalyst and temperature (d) initial concentration of reactive. Answer: (d) initial concentration of reactives. Question 15. For a certain reaction toA → bB, the reaction rate doubled when the A concentration increased four times. The reaction of the ot rate is equal to (a) k[A]a (b) k[A]1/2 (c) k[A]1/a (d) k[A]. Answer: (b) k[A]1/2 Question 16. The Law on Rateschemical reaction, 2no2cl → 2no2 + cl2 is r = k[NO2Cl]. which of the following is the rate control step? (a) no2 + cl → no2cl (b) no2cl + cl → no2 + cl2 (c) no2cl → no2 + cl (d) 2no2cl → 2no2cl + cl2 reply: (c) no2cl → no2 + cl question 17. constant rate of a reaction depends on (a) temperature (b) time (c) initial concentration (d) no response: (a) temperature application 18. ddt on exposure to water decomposes. half life = 10 years. how long will it take for its decomposition to 90?% (a) 50 years (b) 70 years (c) 500 years (d) 700 years. reply: (b) 70 years in question 19. the rate of a first-order reaction is 1.5 × 10-2 mol L-1 min-1 to 0.5 m reactor concentration. the half-life of the reaction is (a) 0.383 mm (b) 23.1mm (c) 8.73 mm (d) 7.53 mm answer: (b) 23.1mm question 20. the rate equation for reaction 2a + b → c is found to be: rate = k [a] [b.] the correct insection of statement to this reaction is that the unit (a) of r must be s-1 (b) t1/2 is constant (c) rate of formation of c is double the disappearance rate of a. (d) k value is independent of the initial concentration of a and b. response: (d) the value of k is independent from the initial concentration of a and b. application 21. the reaction 2 so2 (g) + o2 (g) ̄ so3 (g) is carried out in 1 ship dm3 and 2 vessel dm3 separately. 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 x 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ 1 χ a) the order of a reaction can be determined experimentally. (b) is the sum of the powers of the terms of concentration in the expression of the right of rates. e) not necessarilyon the stoichiometric coefficients. (d) The order of a reaction cannot be fractional. Answer: (d) The order of a reaction cannot be fractional. Question 24. t1/4 may be taken as the time necessary for the concentration of a reactor to descend to 3/4 of its initial value. If the constant rate for a first-order reaction is K, then t1/4 can be written as (a) 0.10/K (b) 0.29/K (c) 0.69/K (d) 0.73/K Response: (b) 0.29/K Question 25. Collision The theory is applicable to (a) first-order reactions (b) zero-order reactions (c) biomolecular reactions (d) intramolecular reactions. Answer: (c) Biomolecular reactions Question 26. The reaction A → B follows the first order kinetics. The time spent for 0.8 A to produce 0.6 B is 1 hour. What is the time needed to convert 0.9 harassment of A to produce 0.675 harassment of B? (a) 1 hour (b) 0.5 hour (c) 0.25 hour (d) 2 hours. Answer: Question 27. The potential energy diagram in the R → P reaction is given. The reaction corresponds to energy. (a) a (b) b (c) c (d) a + b Reply: Question 28. The reaction rate between two reactives A and B decreases by a factor of 4 if the concentration of reactor B is doubled. The order of this reaction to reactor B is (a) 2 (b) -1 (c) 1 (d) -2 Response: (d) -2 Question 29. By reaction to A → xP, when [A] = 2.2 mM the rate was found at 2.4 mMs-1. By reducing the concentration of A to half, the rate changes to 0.6 mMs-1. The reaction order compared to A is (a) 1.5 (b) 2.0 (c) 2.5 (d) 3.0 Response: (b) 2.0 Question 30. The semi-levels of two samples are 0.1 and 0.4 seconds. Their respective concentrations are 200 and 50 respectively. What is the order of reaction? (a) 0 (b) 2 (c) 1 (d) 4 Response: (b) 2 Question 31. In a first-order reaction, the concentration of the reactor decreases from 800 mol/dm3 to 50 mol/dm3 in 2 × 104 sec. The constant rate for reaction in sec-1 (a) 2 × 104 (b)× 10-5 (c) 1.386 × 10-4 (d) 2 × 10-4 Response: (c) 1.386 × 10-4 Question 32. For reaction A + B → C + D, doubling the concentration of both reactionants increases the reaction rate of 8 times and doubling the concentration of only B simply doubles the reaction rate. The tax law is indicated as (a) r = k[A]\(\frac {1}{2}\) [B]\(\frac {1}{2}\\\\) (b) r = k [A]2 (c) r – k [A]2 [B] (d) r = k [A] [B] [B] [B] [B] [B]]] Question 33. In Arrhenius plpt, interception is equal to (a) -Ea/R (b) ln A (c) ln k (d) log10 to Reply: Question 34. The constant rate for reaction 2N2O5 → 4NO2 + O2 is 3.0 × 10-5 sec-1. If the rate is 2.40 × 10-5 mol litre-1 sec-1, then the concentration of N2O5 (in mol litre-1) is: (a) 1.4 (b) 1.2 (c) 0.04 (d) 0.8 Response: Question 35. When a biochemical reaction is carried out in the laboratory from the outside of the human body in the absence of enzyme, then the reaction rate obtained is 10-6 times, so the reaction activation energy in the presence of enzyme is: (a) 6/RT (b) Pis required (c) Different from Ea obtained in the laboratory (d) Can not, say nothing Answer: (c) Different from Ea obtained in laboratory Question 36. If «I» is the intensity of the absorbed light and «C» is the concentration of AB for the photochemical process AB + hv → AB+, the training rate of AB* is directly proportional to: (a) C (b) l2 (d) Cl. Question 37. In the following reaction, how is the rate of emergence of the underlined product concerning the disappearance rate of the underlined reactor? 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